Synthesis and Characterization of CaFe2O4 Spinel as Photocatalyst for Hydrogen Production
Synopsis
CaFe2O4 photocatalyst was successfully synthesized by nitrate route using La(NO3)3.6H2O, and Fe(NO3)3.9H2O as metal ion. The material was characterized by various techniques including TGA-DT, XRD, FT-IR, UV-visible, SEM-EDX, XPS and electrochemical analysis. The photocatalytic activity of the CaFe2O4 was successfully tested for hydrogen production H2 under visible light irradiation. A pure phase of CaFe2O4 is obtained at 850 C° with an orthorhombic structure and an average crystallite size of 31 nm. The photocatalytic activity reveals an optimal H2 production of 189 μmol within 30 min at 50°C in NaOH medium and a catalyst mass of 100 mg, under visible light irradiation.
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